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SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 03/13/2008
Date Updated: 11/09/2007
Version 1.6
Section 1 - Product and Company Information
Product Name ZEOLITE
Product Number 96096
Brand FLUKA
Company Sigma-Aldrich Canada, Ltd
Address 2149 Winston Park Drive
Oakville ON L6H 6J8 CA
Technical Phone: 9058299500
Fax: 9058299292
Emergency Phone: 800-424-9300
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
ZEOLITES 1318-02-1 No
Synonyms Abscents 3000 * Agrolithe 15/25 * Aid Plus OCMA *
Aluminosilicates, zeolites * Bactekiller BM 101A
* Bactekiller BM 102A * Bactekiller BM 501A *
Bactekiller MB * Baylith AC 6184 * Calsit *
Coratyl G * Crystal structure types, zeolites *
CS 100 * CS 100 (zeolite) * CS 100S * EZA Zeolite
A * GRZ 1 * Harmony 70 * Ionsiv * JE 15P *
KC-Perlkator D 10E * KKh 100 * LM 104 * LM 108 *
LM 204 * LM 208 (zeolite) * LMS 9611 *
Microzeokan 8 * MZ 3 * NA 100 * NC 300 *
Neuronizeon SP 3000 * Radiolite * SGK 1 *
Siliporite NK 10 * Silton B 50 * Silton B-MZ 260
* Silton CPT 30 * Silton LP 75 * SK 40 * Spansorb
C * SSZ 37 * Sylosiv 100 * T 134 * Tomix 550 *
TSZ 300 * Ukazil X 100 * Wessalith 80 * XH 9 * XH
600 * Y-SK 40 * Z 3125 * ZB 200 * ZB 400 *
Zeofill * Zeokar * Zeokar 2 * Zeokar 3 * Zeolite
1014 * Zeolite 1424 * Zeolite 24P * Zeolite
particles * Zeolith * Zeolith 225 * Zeolith
Taylor * Zeolum * Zeolum SA * Zeomic * Zeosorb *
Zeostar CA 100P * Zeostar CA 110P
RTECS Number: ZG6800000
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Caution: Avoid contact and inhalation. Target organ(s): Lungs.
HMIS RATING
HEALTH: 1*
FLAMMABILITY: 0
REACTIVITY: 0
NFPA RATING
HEALTH: 1
FLAMMABILITY: 0
REACTIVITY: 0
*additional chronic hazards present.
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
DERMAL EXPOSURE
In case of contact, immediately wash skin with soap and copious
amounts of water.
EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
Section 5 - Fire Fighting Measures
FLASH POINT
N/A
AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Section 6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Exercise appropriate precautions to minimize direct contact with
skin or eyes and prevent inhalation of dust.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Avoid inhalation. Avoid contact with eyes, skin,
and clothing. Avoid prolonged or repeated exposure.
FLUKA - 96096 www.sigma-aldrich.com Page 2
STORAGE
Suitable: Keep tightly closed.
SPECIAL REQUIREMENTS
Hygroscopic.
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN
(EU). Respiratory protection is not required. Where protection
from nuisance levels of dusts are desired, use type N95 (US) or
type P1 (EN 143) dust masks.
Hand: Protective gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
Section 9 - Physical/Chemical Properties
Appearance Physical State: Solid
Property Value At Temperature or Pressure
Molecular Weight N/A
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density N/A
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
Section 10 - Stability and Reactivity
FLUKA - 96096 www.sigma-aldrich.com Page 3
STABILITY
Stable: Stable.
Conditions to Avoid: Moisture.
Materials to Avoid: Strong acids, Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Nature of decomposition products
not known.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: May be harmful if swallowed.
TARGET ORGAN(S) OR SYSTEM(S)
Lungs.
SIGNS AND SYMPTOMS OF EXPOSURE
Prolonged exposure can cause: Damage to the lungs.
TOXICITY DATA
Oral
Rat
> 10,000 mg/kg
LD50
Skin
Rabbit
> 2,000 mg/kg
LD50
4 H
Inhalation
Rat
> 5,300 mg/m3
LC50
1 H
Inhalation
Rat
2,400.0 - 18,300.0 mg/m3
LC50
IRRITATION DATA
Skin
Rabbit
Remarks: Mild irritation effect
Skin
Human
Remarks: No irritation effect
Eyes
Rabbit
Remarks: Mild irritation effect
Eyes
Rabbit
Remarks: No irritation effect
FLUKA - 96096 www.sigma-aldrich.com Page 4
CHRONIC EXPOSURE - MUTAGEN
Species: Human
Dose: 50 MG/L
Cell Type: lymphocyte
Mutation test: Cytogenetic analysis
Species: Mouse
Route: Intraperitoneal
Dose: 50 MG/KG
Mutation test: Cytogenetic analysis
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
Section 14 - Transport Information
DOT
Proper Shipping Name: None
Non-Hazardous for Transport: This substance is
considered to be non-hazardous for transport.
IATA
Non-Hazardous for Air Transport: Non-hazardous for air
transport.
Section 15 - Regulatory Information
US CLASSIFICATION AND LABEL TEXT
US Statements: Caution: Avoid contact and inhalation. Target
organ(s): Lungs.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: No
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
FLUKA - 96096 www.sigma-aldrich.com Page 5
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2008 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
FLUKA - 96096 www.sigma-aldrich.com Page 6
MATERIAL SAFETY DATA SHEET
Date Printed: 03/13/2008
Date Updated: 11/09/2007
Version 1.6
Section 1 - Product and Company Information
Product Name ZEOLITE
Product Number 96096
Brand FLUKA
Company Sigma-Aldrich Canada, Ltd
Address 2149 Winston Park Drive
Oakville ON L6H 6J8 CA
Technical Phone: 9058299500
Fax: 9058299292
Emergency Phone: 800-424-9300
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
ZEOLITES 1318-02-1 No
Synonyms Abscents 3000 * Agrolithe 15/25 * Aid Plus OCMA *
Aluminosilicates, zeolites * Bactekiller BM 101A
* Bactekiller BM 102A * Bactekiller BM 501A *
Bactekiller MB * Baylith AC 6184 * Calsit *
Coratyl G * Crystal structure types, zeolites *
CS 100 * CS 100 (zeolite) * CS 100S * EZA Zeolite
A * GRZ 1 * Harmony 70 * Ionsiv * JE 15P *
KC-Perlkator D 10E * KKh 100 * LM 104 * LM 108 *
LM 204 * LM 208 (zeolite) * LMS 9611 *
Microzeokan 8 * MZ 3 * NA 100 * NC 300 *
Neuronizeon SP 3000 * Radiolite * SGK 1 *
Siliporite NK 10 * Silton B 50 * Silton B-MZ 260
* Silton CPT 30 * Silton LP 75 * SK 40 * Spansorb
C * SSZ 37 * Sylosiv 100 * T 134 * Tomix 550 *
TSZ 300 * Ukazil X 100 * Wessalith 80 * XH 9 * XH
600 * Y-SK 40 * Z 3125 * ZB 200 * ZB 400 *
Zeofill * Zeokar * Zeokar 2 * Zeokar 3 * Zeolite
1014 * Zeolite 1424 * Zeolite 24P * Zeolite
particles * Zeolith * Zeolith 225 * Zeolith
Taylor * Zeolum * Zeolum SA * Zeomic * Zeosorb *
Zeostar CA 100P * Zeostar CA 110P
RTECS Number: ZG6800000
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Caution: Avoid contact and inhalation. Target organ(s): Lungs.
HMIS RATING
HEALTH: 1*
FLAMMABILITY: 0
REACTIVITY: 0
NFPA RATING
HEALTH: 1
FLAMMABILITY: 0
REACTIVITY: 0
*additional chronic hazards present.
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
DERMAL EXPOSURE
In case of contact, immediately wash skin with soap and copious
amounts of water.
EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
Section 5 - Fire Fighting Measures
FLASH POINT
N/A
AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Section 6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Exercise appropriate precautions to minimize direct contact with
skin or eyes and prevent inhalation of dust.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Avoid inhalation. Avoid contact with eyes, skin,
and clothing. Avoid prolonged or repeated exposure.
FLUKA - 96096 www.sigma-aldrich.com Page 2
STORAGE
Suitable: Keep tightly closed.
SPECIAL REQUIREMENTS
Hygroscopic.
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN
(EU). Respiratory protection is not required. Where protection
from nuisance levels of dusts are desired, use type N95 (US) or
type P1 (EN 143) dust masks.
Hand: Protective gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
Section 9 - Physical/Chemical Properties
Appearance Physical State: Solid
Property Value At Temperature or Pressure
Molecular Weight N/A
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density N/A
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
Section 10 - Stability and Reactivity
FLUKA - 96096 www.sigma-aldrich.com Page 3
STABILITY
Stable: Stable.
Conditions to Avoid: Moisture.
Materials to Avoid: Strong acids, Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Nature of decomposition products
not known.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: May be harmful if swallowed.
TARGET ORGAN(S) OR SYSTEM(S)
Lungs.
SIGNS AND SYMPTOMS OF EXPOSURE
Prolonged exposure can cause: Damage to the lungs.
TOXICITY DATA
Oral
Rat
> 10,000 mg/kg
LD50
Skin
Rabbit
> 2,000 mg/kg
LD50
4 H
Inhalation
Rat
> 5,300 mg/m3
LC50
1 H
Inhalation
Rat
2,400.0 - 18,300.0 mg/m3
LC50
IRRITATION DATA
Skin
Rabbit
Remarks: Mild irritation effect
Skin
Human
Remarks: No irritation effect
Eyes
Rabbit
Remarks: Mild irritation effect
Eyes
Rabbit
Remarks: No irritation effect
FLUKA - 96096 www.sigma-aldrich.com Page 4
CHRONIC EXPOSURE - MUTAGEN
Species: Human
Dose: 50 MG/L
Cell Type: lymphocyte
Mutation test: Cytogenetic analysis
Species: Mouse
Route: Intraperitoneal
Dose: 50 MG/KG
Mutation test: Cytogenetic analysis
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
Section 14 - Transport Information
DOT
Proper Shipping Name: None
Non-Hazardous for Transport: This substance is
considered to be non-hazardous for transport.
IATA
Non-Hazardous for Air Transport: Non-hazardous for air
transport.
Section 15 - Regulatory Information
US CLASSIFICATION AND LABEL TEXT
US Statements: Caution: Avoid contact and inhalation. Target
organ(s): Lungs.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: No
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
FLUKA - 96096 www.sigma-aldrich.com Page 5
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2008 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
FLUKA - 96096 www.sigma-aldrich.com Page 6