MATERIAL SAFETY DATA SHEET
AG 101 SOLVENT
3. HAZARDS IDENTIFICATION
Harmful if inhaled or swallowed. Causes skin and eye irritation. Suspect cancer hazard. See Section 11,
"Toxicological Information". High vapour concentrations may cause drowsiness. See "Other Health
Effects" Section. Can decompose at high temperatures forming toxic gases. Contents may develop
pressure on prolonged exposure to heat.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Product is irritating to the nose, throat and respiratory tract. See "Other Health Effects" Section.
Inhalation:
Skin contact can cause irritation, especially under the finger nails (and other confined spaces such as
under rings or watch bands). Prolonged and repeated contact may lead to dermatitis. May cause
defatting, drying and cracking of the skin.
Skin Contact:
Not likely to be absorbed through the skin.
Skin Absorption:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website: http:\\www.brenntag.ca
WHMIS#:
00064491
Index:
2007 May 31
PRODUCT IDENTIFICATION
AG 101 Solvent.
Product Name:
2008 April 22
Date of Revision:
Effective Date:
HCI3348/08B
Not available.
Chemical Name:
Not applicable.
Synonyms:
Halogenated hydrocarbons.
Chemical Family:
C3H7Br.
Molecular Formula:
Industrial solvent, cleaner, degreaser. Consult Product Technical Literature.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
D-2A: Very Toxic (carcinogen)
D-2B: Toxic (respiratory tract, skin & eye
irritant)
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
1-Bromopropane
106-94-5
10 ppm
90-95
Butylene Oxide
106-88-7
—
< 1
AG 101 Solvent
Brenntag Canada Inc.
Date of Revision:
2008 April 22
WHMIS Number :
00064491
Page 2 of 7
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical attention
IMMEDIATELY.
Inhalation:
Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and
water. If irritation, redness, or a burning sensation develops and persists, obtain medical advice.
Skin Contact:
Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during
flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not
convulsing, rinse mouth out but do not swallow. IMMEDIATELY contact local Poison Control Centre.
Vomiting should only be induced under the direction of a physician or a poison control centre. If
spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus,
rinse mouth and administer more water. IMMEDIATELY transport victim to an emergency facility.
Ingestion:
Treat symptomatically. Medical conditions that may be aggravated by exposure to this product include
diseases of the skin, eyes or respiratory tract.
Note to Physicians:
Vapours from this product are irritating to the eyes. Splashes to the eye may cause irritation, redness
and pain.
Eye Contact:
Ingestion is not a likely route of exposure.
Ingestion:
May cause irregular pulse, systemic effects and central nervous system (CNS) depression. CNS
depression is characterized by headache, dizziness, drowsiness, nausea, vomiting and incoordination.
Severe overexposures may lead to coma and possible death due to respiratory failure. (3)
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):
Does not flash. (3)
490. (3)
4.0. (3)
7.8. (3)
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include hydrogen halides, bromide ions, hydrogen
bromide, hydrobromic acid and oxides of carbon, bromine, n-Propyl Bromide and irritating gases.
Hazardous Combustion
Products:
Closed containers exposed to heat may explode. Spilled material may cause floors and contact
surfaces to become slippery.
n-Propyl Bromide is listed as flammable by NFPA 325: Guide to Fire Hazard Properties of Flammable
Liquids, Gases and Volatile Solids, 1994 Edition. However, tests by the manufacturer have
demonstrated that this product is not flammable. (8)
Unusual Fire or Explosion
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Foam. Dry chemical, carbon dioxide or water spray. Use media appropriate for surrounding fire and/or
materials. Do not use high volume water jet.
Fire Extinguishing Media:
FIRE FIGHTING
INSTRUCTIONS
Use water spray to cool fire-exposed containers or structures. Use water spray to disperse vapours.
Use self-contained breathing apparatus and special protective clothing. Isolate materials that are not
involved in the fire and protect personnel. Spills on hot fibrous insulation may lead to the lowering of the
autoignition temperature possibly resulting in spontaneous combustion.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective
Equipment:
AG 101 Solvent
Brenntag Canada Inc.
Date of Revision:
2008 April 22
WHMIS Number :
00064491
Page 3 of 7
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons,
property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS.
Wear respirator, protective clothing and gloves. Clean up immediately to eliminate slipping hazard. Do
not allow to enter sewers or watercourses. Spilled material may cause floors and contact surfaces to
become slippery. Collect product for recovery or disposal. For release to land, or storm water runoff,
contain discharge by constructing dykes or applying inert absorbent; for release to water, utilize
damming and/or water diversion to minimize the spread of contamination. Ventilate enclosed spaces.
Notify applicable government authority if release is reportable or could adversely affect the environment.
Containment and Clean-Up
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be
under internal pressure. These should be cooled and carefully vented before opening. A face shield
and apron should be worn. Vent container frequently, and more often in warm weather, to relieve
pressure.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing vapours and aerosols. Avoid contact with eyes,
skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated clothing
thoroughly before re-use. Do not use cutting or welding torches on empty drums that contained this
material/product.
Other Precautions:
STORAGE
See below.
Storage Temperature (°C):
General exhaust is acceptable.
Ventilation Requirements:
Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers
closed. Do not expose sealed containers to temperatures above 40° C. Avoid moisture contamination.
Protect from direct sunlight. Protect against physical damage.
Storage Requirements:
Confirm suitability of any material before using. Materials of construction for storing the product
include: High Density Polyethylene (HDPE) and lined steel. Equipment for storage, handling or
transportation should NOT be made of: Polycarbonate, Acrylic Polymer, ABS, PVC, Polystyrene.
Consult Product Technical Literature.
Special Materials to be Used for
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this
product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific
protective devices at your workplace.
ENGINEERING CONTROLS
Local exhaust ventilation preferred. Make up air should be supplied to balance air that is removed by
local or general exhaust ventilation. Ventilate low lying areas such as sumps or pits where dense
vapours may collect.
Engineering Controls:
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles
when there is potential for eye contact. Contact lenses should not be worn when working with this
material.
Eye Protection:
Gloves and protective clothing made from viton should be impervious under conditions of use. Prior to
use, user should confirm impermeability. Discard contaminated gloves. Consult Product Technical
Literature.
Skin Protection:
AG 101 Solvent
Brenntag Canada Inc.
Date of Revision:
2008 April 22
WHMIS Number :
00064491
Page 4 of 7
No specific guidelines available. A NIOSH/MSHA-approved air-purifying respirator equipped with
organic vapour cartridges for concentrations up to 100 ppm n-Propyl Bromide. (3) An air-supplied
respirator if concentrations are higher or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in
the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check
to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If
the seal is no longer good, you may need a new respirator. (4)
Respiratory Protection:
Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical
handling area. Take all precautions to avoid personal contact.
Other Personal Protective
Equipment:
EXPOSURE GUIDELINES
SUBSTANCE
ACGIH TLV
(STEL)
OSHA PEL
(TWA) (STEL)
NIOSH REL
(TWA) (STEL)
1-Bromopropane
—
---
---
---
---
Liquid.
Clear liquid.
Sweet odour.
Not available.
69.
-110.
110.8 ; 143 (25°C).
4.3.
1.32.
Not available.
0.42 centipoise (25°C).
Not applicable.
2.4 g/l.
Not available.
Not available.
Not available.
> 800 g/1.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
Does not flash. (3)
Flashpoint (°C):
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable under recommended storage conditions.
Under usage conditions: Product acid acceptance test should be carried out periodically to ensure
stability of product (Details available on request).
Under Normal Conditions:
Not flammable.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
Water contamination of this product, especially under elevated temperature reflux as in a vapour
degreasing unit, may lead to the hydrolysis of the product with a drop in pH and the production of free
acid. This may lead to an unexpectedly rapid depletion of the acid stabilizer normally present. In rare
cases, the product may become corrosive. Consult vendor information relative to "Acid Acceptance
Testing."
Decomposes at 204.4 °C.
Conditions to Avoid:
Strong oxidizers. Alkali metals. Calcium. Finely powdered aluminum.
Materials to Avoid:
Thermal decomposition products are toxic and may include hydrogen halides, bromide ions, hydrogen
bromide, hydrobromic acid and oxides of carbon, bromine, n-Propyl Bromide and irritating gases.
Decomposition or Combustion
Products:
AG 101 Solvent
Brenntag Canada Inc.
Date of Revision:
2008 April 22
WHMIS Number :
00064491
Page 5 of 7
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
AG 101 Solvent
4 260 mg/kg (3)
---
31 625 mg/m³ (3)
Butylene Oxide: Possibly carcinogenic to humans. (IARC-2B)
Carcinogenicity Data:
Although there is no direct evidence that exposure of people to 1-Bromopropane adversely affects
reproduction or development, studies reviewed by the expert panel and more recent studies in rats
show that exposure to 1-Bromopropane can adversely affect reproduction and development. (7)
The critical reproductive toxicity study in animals was a two-generation, inhalation study. It showed
exposure of rats to 250 ppm or greater altered numerous reproductive endpoints in both females and
males. These included decreased prostate weight, decreased sperm motility and percent normal sperm
in males and decreased litter size, decreased numbers of implantation sites, increased ovarian follicular
cysts, and increased estrous cycle length in females. The panel determined that no adverse
reproductive effects were observed at an exposure concentration of 100 ppm. (7)
Another recent study showed that female rats exposed 8 hours per day to 200, 400, or 800 ppm 1-BP
for 7 to 12 weeks showed a significant, dose-dependent increase in the number of irregular estrous
cycles, with extended diestrus at 400 ppm (Yamada et al., 2003). Additionally, examination of the
ovaries showed a dose-dependent reduction in the number of normal antral (or mature) follicles at
doses of 200 and 400 ppm. This effect is consistent with reduced fertility and litter sizes reported in
earlier studies. Interestingly, the number of primordial follicles was not significantly reduced in any of
the 1-Bromopropane exposure groups. The authors suggest that antral follicle counts may provide a
more sensitive indicator of 1-Bromopropane-induced female reproductive dysfunction than other
endpoints such as estrous length. (7)
Reproductive Data:
This product produced negative results for mutagenicity (Ames Test). (3)
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization
Data:
None known.
Synergistic Materials:
Butylene Oxide: Cancers of the respiratory system have been observed in rats and mice exposed by
inhalation. Negative results have been obtained in mice exposed by skin application. The International
Agency for Research on Cancer (IARC) has concluded that this chemical is possibly carcinogenic to
humans (Group 2B). (4)
When n-Propyl Bromide was tested for genetic toxicity, it tested negative for dominant lethal activity in
rats at 400 mg/Kg/day. This dose was given to male rats prior to breeding once weekly for eight
successive weeks. No difference in mating performance was observed. (9)
The frequency of fertile matings, mean number of corpora lutea, number of implants per female,
number of live embryos per female and the dominant lethal index was comparable to the negative
control group at weeks 1 through 8 after treatment. The frequency of dead implants was higher during
week eight compared to the controls, but no increases in dominant lethal index were observed during
the previous seven weeks. The frequency of dead implants in the treated group was similar to that of
the controls during weeks one through seven. (9)
Other Studies Relevant to
Material:
12. ECOLOGICAL INFORMATION
Harmful to aquatic life at low concentrations.
n-Propyl Bromide: 96-hour LC50 (Fathead Minnow) = 673 mg/L
Ecotoxicity:
Not readily biodegradable. Low bioaccumulation potential. (3) Can be dangerous if allowed to enter
drinking water intakes. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds,
or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
Not applicable.
Deactivating Chemicals:
AG 101 Solvent
Brenntag Canada Inc.
Date of Revision:
2008 April 22
WHMIS Number :
00064491
Page 6 of 7
This information applies to the material as manufactured. Reevaluation of the product may be required
by the user at the time of disposal since the product uses, transformations, mixtures and processes
may influence waste classification. Dispose of waste material at an approved (hazardous) waste
treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue and can be dangerous. Empty drums should be completely
drained, properly bunged and promptly returned to a drum reconditioner. Do not expose such containers
to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury
or death. Do not dispose of package until thoroughly washed out. Dispose of waste material at an
approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial
and federal regulations.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s): Not applicable. Placard: Not applicable.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s): Not applicable. Placard: Not applicable.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
D-2A: Very Toxic (carcinogen)
D-2B: Toxic (respiratory tract, skin & eye
irritant)
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Respiratory Tract, Skin and Eye Irritant.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA: 2 Health, 0 Fire, 0 Reactivity (6)
Text22:
HMIS: Health, Fire, Reactivity ()
INTERNATIONAL
Not available.
16. OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons,
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2007, American Conference of Governmental Industrial Hygienists, Cincinnati, 2007.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
AG 101 Solvent
Brenntag Canada Inc.
Date of Revision:
2008 April 22
WHMIS Number :
00064491
Page 7 of 7
NTP-CERHR Monograph on the Potential Human Reproductive and Developmental Effects of 1-Bromopropane, October 2003,
NIH Publication No. 04-4479.
7.
Correspondence with supplier, dated January 11, 1999.
8.
Correspondence with supplier, dated July 27, 1998.
9.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith
by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained
herein. This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1
Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9
Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2
Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6
Phone: (416) 259-8231 Facsimile: (416) 259-5333
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
Phone: (902) 468-9690 Facsimile: (902) 468-3085
____________________________________________________________________________________________________________
Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.