ATEVA EVA COPOLYMERS




PRODUCT DISTRIBUTED BY / PRODUIT DISTRIBUÉ PAR


Brenntag Canada Inc. WHMIS Number: 00066352
43 Jutland Road. Index: HCI5492/08C
Toronto, Ontario Effective Date: 2008 August 19
M8Z 2G6 Date of Revision: 2008 August 19
(416) 259-8231 Website: http://www.brenntag.ca
_______________________________________________________________________________________________

EMERGENCY TELEPHONE NUMBERS / EN CAS D'URGENCE

Toronto, ON (416) 226-6117 Montréal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
_______________________________________________________________________________________________


This document consists of an English MSDS.

Le présent document comprend une fiche signalétique en anglais.




READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.

LIRE LA FICHE SIGNALÉTIQUE EN ENTIER POUR UNE ÉVALUATION COMPLÈTE DES DANGERS QUE
REPRÉSENTE CE PRODUIT



MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 1 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM

Section 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name:
Ateva® EVA Copolymers




“Ateva®” is a Registered Trademark of AT Plastics.
Ateva® 2604A



Ateva® 2803A, 2803G, 2810A, 2815A, 2820A, 2821A, 2825A,
Ateva® 2825AC, 2830A, 2830AC, 2842A, 2842AC, 2850A,
Ateva® 2861A, 2861AU




Company Address:
AT Plastics




4405-101 Avenue




P.O. Box 428




Edmonton, Alberta, Canada




T5J 2K1





Tel: (780) 468-0800




Web: www.atplastics.com

Product Use:
Manufacture of extruded products.

Section 2





HAZARDS IDENTIFICATION

Emergency Overview:
Appearance: Product is a clear to white solid, in pellet, granular or powder form. Slight vinegar
like odour.
Caution: This material is combustible and will burn in fire and emit irritating smoke. Powdered
material may form explosive dust – air mixtures. Dusts and heat – released air emissions may
be irritating to the eyes, skin and respiratory system. Spilled product may create a slipping



hazard. Released pellets should be kept away from storm sewers and other entry into aquatic
systems. Molten resin cause severe thermal burns.

This product is considered hazardous as defined in OSHA Hazard Communication standard,
29 CFR 1910.1200, based on the presence of vinyl acetate (maximum 0.3%).

This product is a controlled product under Canadian WHMIS regulations.

Cont’d

MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 2 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM










Potential Health Effects:
Inhalation: Inhalation of dust may cause respiratory irritation. Fumes produced during thermal
processing may cause irritation.
Eyes: Solid or dust may cause irritation or corneal injury due to mechanical action.
Skin: Prolonged contact is essentially non-irritating to skin. There can be mechanical injury, if
impacted with skin. Under normal processing conditions, material is heated to elevated
temperatures; contact with the material may cause thermal burns. No adverse effects
anticipated by skin absorption.
Ingestion: Very low toxicity if swallowed. Harmful effects not anticipated from swallowing
small amounts. Swallowing may cause choking.

Carcinogenicity Information:
Contains low levels (<0.3%) of residual vinyl acetate. Vinyl acetate has been classified by IARC
as 2B, possibly carcinogenic to humans; ACGIH Classification: Group A3, Animal carcinogen
with unknown relevance to humans (see Section 11).


Section 3

COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS


CAS NUMBER

%

Ethylene-Vinyl Acetate Copolymer
24937-78-8


> 99
Vinyl Acetate



108-05-4


< 0.3

Base Resin Molecular Formula:
[CH2CH2]n [CH2CH(02CCH3)-]m

The product may contain varying levels of process aids.

Section 4






FIRST AID MEASURES

Solid product is neither an irritant nor gives off hazardous vapours at ambient temperatures.

Eyes:
The material is non-irritating upon contact, except upon impact as any foreign
particle in the eye. In the case of irritation caused by fine dust or fumes during
thermal processing, rinse opened eyes for several seconds under running water.
If irritation persists, consult physician.











Cont’d

MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 3 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM

Skin:
Not a hazard at ambient conditions. Washing hands is preferable after use.
Contact with heated material may cause thermal burns. Do not attempt to
remove material from skin. Cool rapidly with cold water. Obtain medical
treatment.
Ingestion:
Material is not expected to cause an ingestion problem. No first aid procedures
are required. If necessary, get medical advice.

Inhalation:
Pellet inhalation is unlikely due to physical form. Product fines and dust may
cause mild respiratory irritation.

Note to Attending Physician: If molten polymer is in contact with skin, treat as any thermal
burn, after decontamination. No specific antidote. Treatment of exposure should
be directed at the control of symptoms and the clinical condition of the patient.

Section 5





FIRE FIGHTING MEASURES

Flammable Properties:

Flash Point:


Not Available

Flash Point Method:

Not Applicable

Upper Flammability Limit:
Not Applicable

Lower Flammability Limit:
Not Applicable

Autoignition Temperature:
330ºC – 410ºC (Estimated)
Under fire conditions, the solid pellets will readily burn and emit a
heavy, irritating smoke. Do not permit dust to accumulate, as
high concentrations of airborne dust may form explosive mixture
with air. May accumulate static charge.
Combustion products may include and are not limited to carbon
monoxide, carbon dioxide, vinyl acetate, acetic acid.








Extinguishing Media:
Water fog or fine spray, dry chemical fire extinguishers, carbon
dioxide fire extinguishers and foam. General purpose synthetic
foams (including AFFF type) or protein foams are preferred.












Cont’d

MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 4 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM











Fire Fighting Instructions:
Keep unnecessary personnel away. Soak thoroughly with water
to cool and prevent re-ignition.











If material is molten, do not apply direct water stream. Use fine
water spray or foam. Cool surroundings with water to localize
fire zone. Hand held dry chemical or carbon dioxide
extinguishers may be used for small fires. Dust explosion
hazard may result from forceful application of fire extinguishing
agents.

Protective Equipment for Fire
Fighters:
Wear positive-pressure, self-contained breathing apparatus
(SCBA) and protective fire fighting clothing (includes fire fighting
helmet, coat, pants, boots and gloves).

Section 6




ACCIDENTAL RELEASE MEASURES

In the event of an Accidental Release:
Personal Protection:

Isolate area. Extinguish or remove possible ignition sources.
Collect product for re- use or disposal. Sweep up immediately to
eliminate slipping hazard.

Environmental Protection:
Prevent from entering soil, ditches, sewers, waterways and
ground water. Notify applicable government authority if release
is reportable or could adversely affect the environment.

Section 7





HANDLING AND STORAGE

Small amounts of fine dust & shavings may be created during passage through air conveying
system. Ground and bond equipment and containers to prevent a static charge build-up. Avoid
high temperatures, sparks, open flames and all other sources of ignition in areas where fine dusts
may be produced.

Storage Temperature (ºC):
Ambient temperatures.

Storage Requirements:
Should be stored under cover to prevent degradation due to
sunlight.

Shelf Life:


Maximum of five years, if stored properly.



MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 5 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM

Section 8

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines: Follow all applicable exposure limits for particulates (insoluble), not
otherwise regulated.

ACGIH:

10 mg/m3 TWO (inhalable particles); 3 mg/m3 TWA (respirable particles)
[related to Particulates (insoluble or poorly soluble) not otherwise
specified (PNOS)].

OSHA:

15 mg/m3 TWA (total dust); 5 mg/M3 TWA (respirable fraction) (related
to Particulates not otherwise regulated).



Other applicable exposure limits:


Vinyl Acetate


ACGIH TWA 10ppm


STEL 15ppm

Engineering Controls: Good general ventilation is acceptable for most conditions.
Local ventilation must be used over processing equipment to maintain
vinyl acetate concentration below 10 ppm.

Personal Protective
Equipment:
Eyes/Face: Wear safety glasses with side shield. Wear face shield
during thermal processing, when cleaning condensed fumes from hoods,
ducts and other surfaces.
Skin Protection: Wear thermal insulating glove when handling molten
product.
Respiratory Protection: None normally needed. A NIOSH/MSHA
approved-respirator, with combined organic vapour/dust, mist or fume
cartridges, if required.










MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 6 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM

Section 9

PHYSICAL AND CHEMICAL PROPERTIES

Physical State/Appearance:



Solid, pellets, granules or powder
Odour:





None to slight vinegar-like odour
Odour Threshold:




Not Available
pH:






Not Applicable
Melting Point:




60ºC - 80ºC
Boiling Range:




Not Applicable
Flash Point:





Not Applicable
Evaporation Rate:




Not Applicable
Upper/Lower Flammability Limits:


Not Applicable
Vapour Pressure:




Not Applicable
Vapour Density:




Not Applicable
Specific Gravity (Water = 1):



0.910 – 0.950
Solubility:





Not soluble in water
Partition Coefficient: Octanol/Water:

Not Available
Auto-Ignition Temperature:



> 330ºC (estimated)
Decomposition Temperature:


> 300ºC (estimated)
% Volatiles by Volume:



Negligible

Section 10



STABILITY AND REACTIVITY

Chemical Stability:
Stable under ambient conditions

Conditions to Avoid:
Avoid strong oxidizing agents. Avoid processing material over 210ºC.

Incompatible Materials:
Organic solvents may partially dissolve and degrade the polymers. May react with strong
oxidizing agents.

Hazardous Decomposition Products:
Decomposition products may include and are not limited to carbon dioxide, carbon monoxide,
vinyl acetate, acetic acid and other hydrocarbon oxidation products. Inhalation of these
decomposition products may be hazardous.

Hazardous Polymerization:
Will not occur.



MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 7 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM

Section 11


TOXICOLOGICAL INFORMATION

Acute Toxicity

General Information: Material is considered biologically inert. Exposure to high levels of dust or
Heated fumes may cause irritation.

Chronic Toxicity:
The product may contain low levels (<0.3%) of vinyl acetate monomer.

Carcinogenicity Data: Oral–VA was not carcinogenic in a lifetime drinking water study in rats at
concentrations of 200 to 5000 ppm. Other studies were not conducted according to current
scientific principles and guidelines (e.g., too few animals, lack of experimental details). In another
drinking water study, vinyl acetate was reported to cause an increased incidence of oral cavity
and upper digestive tract tumors at 10000 ppm in rats and mice, but not at lower concentrations.
Inhalation- VA did not cause treatment related tumors in mice in a lifetime inhalation study at
concentrations of 50 to 600 ppm. In rats, treatment-related nasal tumors were reported at 600
ppm, but not at 50 or 200 ppm.

ACGIH Classification: A3, Animal Carcinogen (available evidence suggests that the agent is
not likely to cause cancer in humans except under uncommon or unlikely routes or levels of
exposure). IARC: 2B, possibly carcinogenic to humans (based on inadequate human data and
limited animal data).

Reproductive Effects: There is no reported data.

Mutagenicity Data:
There is no reported data.

Synergistic Materials: There is no reported data.

Other Health Effects: None known.

Inhalation: No toxic effects are known to be associated with inhalation of dust from this material.
Dust, if formed during improper handling, is irritating to the nose, throat and respiratory tract, and
may cause coughing and sneezing. Processing may release vapours which are irritating to the
eyes, nose and respiratory tract.

Other Health Effects: This product contains vinyl acetate (<0.3%) which is classified according
to the Controlled Products Regulations as a skin, eye and respiratory tract irritant. However, this
ingredient is bound within the product matrix and exposure to it unlikely under normal conditions.
(See also Section 4).




MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 8 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM

Section 12


ECOLOGICAL INFORMATION

Ecotoxicity: The material is biologically inert and non-toxic.
Persistence/Degradability: It is stable in aquatic systems or in a landfill.
Bioaccumulation/Accumulation: The pellets may accumulate in the digestive systems, if
ingested by fish or wildlife.
Mobility: If released into aquatic systems, the product will float and it will flow with the water
current. The product should be recovered from water.
Deactivating Chemicals: None required.

Section 13


DISPOSAL CONSIDERATIONS

The product is not a hazardous waste according to US RCRA and Canadian CEPA Regulations.
Waste Disposal Methods: Dispose of waste material at a suitable landfill site, or at an
approved waste incineration facility in accordance with applicable local, provincial, state, and
federal regulations.
For unused product, the preferred options include sending to a licensed recycler, reclaimer.


Section 14


TRANSPORT INFORMATION

US DOT Information:

Shipping Name: Not regulated as a Hazardous Material for Transportation.
Canadian TDG Information:
Shipping Name: Not regulated as a Hazardous Material for Transportation.

Section 15


REGULATORY INFORMATION

Ethylene Vinyl Acetate (CAS# 24937-78-8) and all ingredients are listed in the following chemical
inventories:
-
USA – TSCA
-
Canada – DSL
-
European EINECS are exempt from the listings, all monomers are listed.
-
Australian AICS
Cont’d


MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 9 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM

This product contains <0.3% residual monomer, vinyl acetate (CAS# 108-05-4). Vinyl acetate is
required to be reported under:
SARA 302: (40 CFR 355 Appendix A)
SARA 313: (40 CFR 372.65)
CERCLA: (40 CFR 302.4)
SARA 302: 1000 lb. TPQ
CERCLA: 5000 lb. Final RQ

For information on food-contact compliance statement, please contact your account manager.

WHMIS Classification: D2A
Classified D2A due to the presence of residual vinyl acetate, which may be released during storage
or thermal processing.

CONEG Status: Complies with Regulation

Ozone Depleting Substances: Complies with Clean Air Act Amendment of 1990


Section 16 OTHER INFORMATION

INFORMATION SOURCES

1. Supplier's Material Safety Data Sheets

2. RTECS, Registry of Toxic Effects of Chemical Substances, Database via the Scientific
and Technical Information Network (STN).

3. CHEMpendium  CD-ROM produced by Canadian Centre for Occupational Health and
Safety

4. CHEMLIST – Regulated Chemical Listing, Database via Scientific and Technical
Information Network (STN)

This MSDS has been prepared to the standards and guidelines presented in ANSI® Z400.01-2004

Revision History: Section 15. Cont’d



MATERIAL SAFETY DATA SHEET

AT Plastics

A Business of Celanese
Index #: 300.001
Date Issued: March 24, 2006

Revision Date: August 19, 2008

Supercedes: July 19, 2008
ATEVA® EVA COPOLYMER
Transportation Emergency:

Page 10 of 10
800-424-9300 CHEMTREC, 24 hours/day
703-527-3887 Outside USA, Collect calls accepted

Product Information/Customer Service:
800-661-3663

8/19/2008 7:38:00 PM

Legend:
AFFF
Aqueous Film Forming Foam
AICS
Australian Inventory of Chemical Substances
CAS#
Chemical Abstracts Service Registry Number
CERCLA
Comprehensive Environmental Response, Compensation, and Liability Act
CFR
Code of Federal Regulations
DOT
Department of Transportation
ECL
Existing Chemicals List
EINECS
European Inventory of Existing Commercial Chemical Substances
EPA
Environmental Protection Agency
HMIS
Hazardous Materials Identification System
MSHA
Mine Safety and Health Administration
NIOSH
National Institute for Occupational Safety and Health
OSHA
Occupational Safety and Health Administration
PICCS
Philippines Inventory of Chemicals and Chemical Substances
RCRA
Resource Conservation and Recovery Act
SARA
Superfund Amendments and Reauthorization Act of U.S. EPA
TC
Transport Canada
TDG
Transportation of Dangerous Goods Act/Regulations
TLV
Threshold Limit Value
TSCA
Toxic Substances Control Act
TWA
Time-Weighted Average
WHMIS
Workplace Hazardous Materials Information System











The information contained herein is offered only as a guide to the handling of this specific material and has been prepared
in good faith by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions
of use and handling may involve other and additional considerations. No warranty of any kind is given or implied and AT
Plastics Inc. will not be liable for any damages, losses, injuries or consequential damages which may result from the use
of or reliance on any information contained herein. This Material Safety Data Sheet is valid for three years. This product
has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required
by the CPR.

Prepared By:
Sig Sigamani

Regulatory and Product Stewardship

AT Plastics
8040 Dixie Highway
Florence, KY 41042
Tel:
(859) 372-5692
Fax: (859) 372-6382
ssigamani@atplastics.com


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