MATERIAL SAFETY DATA SHEET
STERNPAC, LIQUID
3. HAZARDS IDENTIFICATION
Corrosive! Causes severe skin and eye burns. Contact with mist or spray may cause irritation of
mucous membranes, coughing and difficulty in breathing. See "Other Health Effects" Section. Can
decompose at high temperatures forming toxic gases. Contents may develop pressure on prolonged
exposure to heat.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Inhalation is not a likely route of exposure at normally encountered temperatures. Contact with mist or
spray may cause irritation of mucous membranes, coughing and difficulty in breathing. See "Other
Health Effects" Section.
Inhalation:
Corrosive! Concentrated solutions may cause pain and deep and severe burns to the skin. Prolonged
and repeated exposure to dilute solutions often causes irritation, redness, pain and drying and cracking
of the skin.
Skin Contact:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website: http:\\www.brenntag.ca
WHMIS#:
00061452
Index:
2007 March 15
PRODUCT IDENTIFICATION
Sternpac, Liquid.
Product Name:
2007 March 15
Date of Revision:
Effective Date:
HCI0307/07A
Aluminum Chloride Hydroxide Sulphate.
Chemical Name:
SternPAC; Aluminum, water-soluble salts, n.o.s.; Polyaluminum Chloride;
Polyhydroxosulphatoaluminum Chloride.
Synonyms:
An aqueous solution of hydroxoaluminum and hydroxosulphatoaluminum chlorides.
Chemical Family:
Al13(OH)20(SO4)2Cl15.
Molecular Formula:
Flocculant for water treatment.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
E: Corrosive
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Aluminum Chloride Hydroxide Sulphate
39390-78-3
2 mg/m3 as Al
soluble salts
15 - 40
Sternpac, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 March 15
WHMIS Number :
00061452
Page 2 of 7
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Oxygen administration may
be beneficial in this situation but should only be administered by personnel trained in its use. Obtain
medical attention IMMEDIATELY.
Inhalation:
Prompt removal of the material from the skin is essential. Remove all contaminated clothing and
immediately wash the exposed areas with copious amounts of soap and water for a minimum of 30
minutes or up to 60 minutes for critical body areas. Immerse the exposed part immediately in ice water
to relieve pain and to prevent swelling and blistering. Place cold packs, ice or wet cloths on the burned
area if immersion is not possible. Cover the exposed part with a clean, preferably sterile, lint-free
dressing. Obtain medical attention IMMEDIATELY and monitor breathing and treat for shock for severe
exposure.
Skin Contact:
Immediately flush eyes with running water for a minimum of 30 minutes, preferably up to 60 minutes.
Hold eyelids open during flushing. If irritation persists, repeat flushing. Do not transport victim until the
recommended flushing period is completed unless flushing can be continued during transport.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. DO NOT induce
vomiting. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing
in of vomitus, rinse mouth and administer more water. Obtain medical attention IMMEDIATELY.
Ingestion:
Due to the severely irritating or corrosive nature of the material, swallowing may lead to ulceration and
inflammation of the upper alimentary tract with hemorrhage and fluid loss. Also, perforation of the
esophagus or stomach may occur, leading to mediastinitis or peritonitis and the resultant complications.
(3)
This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has
occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to
prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial
resuscitation and appropriate chemotherapy if respiration is depressed.
Medical conditions that may be aggravated by exposure to this product include neurological and
cardiovascular disorders, diseases of the skin, eyes or respiratory tract, preexisting liver and kidney
disorders.
Note to Physicians:
A single, prolonged skin exposure is not likely to result in the absorption of toxic amounts of the material.
Skin Absorption:
This product causes severe irritation to the eyes with redness and pain, lachrymation (excessive tears)
and conjunctivitis.
Eye Contact:
Corrosive! This product causes severe burning and pain in the mouth, throat and abdomen. Vomiting,
diarrhea and perforation of the esophagus and stomach lining may occur.
Ingestion:
Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation
or onset of pain. Strict adherence to first aid measures following any exposure is essential.
May cause central nervous system (CNS) depression, liver damage and kidney damage. CNS
depression is characterized by headache, dizziness, drowsiness, nausea, vomiting and incoordination.
Severe overexposures may lead to coma and possible death due to respiratory failure. Liver damage is
characterized by the loss of appetite, jaundice (yellowish skin colour), and occasional pain in the upper
left-hand side of the abdomen. Signs and symptoms of kidney damage generally progress from oliguria,
to blood in the urine, to total renal failure.
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):
Non-combustible (does not
burn).
Not applicable.
Not applicable.
Not applicable.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include Chlorine, flammable hydrogen gas,
corrosive hydrochloric acid gas, oxides of carbon, sulphur, aluminum and irritating gases.
Hazardous Combustion
Products:
Reacts with most metals to produce hydrogen gas which could make an explosive mixture with air.
Spilled material may cause floors and contact surfaces to become slippery.
Unusual Fire or Explosion
Hazards:
Sternpac, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 March 15
WHMIS Number :
00061452
Page 3 of 7
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Use media appropriate for surrounding fire and/or materials.
Fire Extinguishing Media:
FIRE FIGHTING
INSTRUCTIONS
Fire-exposed containers should be kept cool by spraying with water to reduce pressure. Spilled material
may cause floors and contact surfaces to become slippery.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons,
property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from
region to region.
See Section 13, "Deactivating Chemicals". Wear protective clothing. Spilled material may cause floors
and contact surfaces to become slippery. Collect product for recovery or disposal. For release to land,
or storm water runoff, contain discharge by constructing dykes or applying inert absorbent; for release
to water, utilize damming and/or water diversion to minimize the spread of contamination. Ventilate
enclosed spaces. Notify applicable government authority if release is reportable or could adversely
affect the environment.
Containment and Clean-Up
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be
under internal pressure. These should be cooled and carefully vented before opening. A face shield
and apron should be worn. Vent container frequently, and more often in warm weather, to relieve
pressure.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing aerosols ( vapours or mists ). Avoid contact with
eyes, skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated
clothing thoroughly before re-use.
Other Precautions:
STORAGE
Ideal storage temperature is 10 to 30 °C ( 3 ) Temperatures above 35 degrees Celsius will cause this
product to scale and product performance will suffer. The typical shelf life of this product is 12 months.
( 3 )
Storage Temperature (°C):
Local exhaust ventilation required. Ventilation should be corrosion proof.
Ventilation Requirements:
Keep containers closed. Store in a clean, cool well ventilated area, away from organic chemicals, strong
bases, strong acids, metal powders, carbides, sulfides, and any readily oxidizable material. Protect
from direct sunlight. Protect against physical damage. Storage tanks should be in a contained area to
control any spills or leaks. Storage area should be equipped with corrosion-resistant floors, sumps and
should have controlled drainage to a recovery tank.
Corrosive residue is most likely to be deposited at process vents or storage tanks, especially during
filling operations. The use of compressed air to force corrosive materials from delivery trucks is of
special concern. Scrubbing the exhaust of these vents is highly recommended. Jurisdictional
regulations should be consulted to determine required practices.
Storage Requirements:
Materials of construction for storing the product include: carbon steel, stainless steel or plastics.
Confirm suitability of any material before using.
Special Materials to be Used for
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this
product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific
Sternpac, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 March 15
WHMIS Number :
00061452
Page 4 of 7
protective devices at your workplace.
ENGINEERING CONTROLS
Local exhaust ventilation required. Ventilation should be corrosion proof. Make up air should be
supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas
such as sumps or pits where dense vapours may collect.
For personnel entry into confined spaces (i.e. bulk storage tanks) a proper procedure must be followed.
It must include consideration of, among other things, ventilation, testing of tank atmosphere, provision
and maintenance of SCBA, and emergency rescue. Use the "buddy" system. The second person
should be in view and trained and equipped to execute a rescue. (4)
Engineering Controls:
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
Use full face-shield and chemical safety goggles when there is potential for contact. Contact lenses
should not be worn when working with this material.
Eye Protection:
Gloves and protective clothing made from neoprene, rubber or plastic should be impervious under
conditions of use. Discard contaminated gloves. Prior to use, user should confirm impermeability.
Skin Protection:
No specific guidelines available. Respiratory protection should not be necessary unless the material is
heated or a mist created. A NIOSH/MSHA-approved full facepiece air-purifying respirator equipped with
acid gas, dust, mist, fume cartridges for concentrations up to 20 ppm. An air-supplied respirator if
concentrations are higher or unknown.
Respiratory Protection:
Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical
handling area. Take all precautions to avoid personal contact.
Other Personal Protective
Equipment:
EXPOSURE GUIDELINES
SUBSTANCE
ACGIH TLV
(STEL)
OSHA PEL
(TWA) (STEL)
NIOSH REL
(TWA) (STEL)
Aluminum Chloride
Hydroxide Sulphate
—
---
---
2 mg/m3 as Al
---
Liquid.
Colourless to pale yellow liquid.
Slight odour.
Not available.
Approximately 102.
Approximately -14 to -10
17. (3)
1.3. (3)
Approximately 1.202 to 1.208
1,202 - 1,208 kg/m3.
Not available.
<1.
Soluble in water.
70.
2.3 - 2.9. (3)
>1.
Not applicable.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not flammable.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition.
Conditions to Avoid:
Sternpac, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 March 15
WHMIS Number :
00061452
Page 5 of 7
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Aluminum Chloride Hydroxide
Sulphate
12 800 mg/kg (3)
---
---
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization
Data:
None known.
Synergistic Materials:
None known.
Other Studies Relevant to
Material:
12. ECOLOGICAL INFORMATION
Not available. May be harmful to aquatic life. Toxicity is primarily associated with pH. Acidic soil
conditions can develop with product present. Higher than normal toxic heavy metal concentrations can
then occur in ground and surface waters.
Aluminum Chloride Hydroxide Sulphate:
96-hour LC50 (Daphnia magna) = 1,400 ppm. (3)
96-hour LC50 (Rainbow Trout) = 1,555 ppm. (3)
48-hour LC50 (Fathead Minnow) = 870 ppm. (3)
48-hour LC50 (Ceriodaphnia dubia) = 2,000 ppm. (3)
Ecotoxicity:
Not available. May be harmful if allowed to enter drinking water intakes. Do not contaminate domestic or
irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
Neutralize carefully with soda ash or sodium bicarbonate to a pH of 6 to 9. Neutralization is expected to
be exothermic. Effervescence may result.
Deactivating Chemicals:
Dispose of waste material at an approved (hazardous) waste treatment/disposal facility in accordance
with applicable local, provincial and federal regulations. Do not dispose of waste with normal garbage,
or to sewer systems.
Waste Disposal Methods:
Empty containers retain product residue (liquid and/or vapour) and can be dangerous. See
"Deactivating Chemicals".
Safe Handling of Residues:
Empty containers retain product residue (liquid and/or vapour) and can be dangerous. Empty drums
should be completely drained, properly bunged and promptly returned to a drum reconditioner. Do not
dispose of package until thoroughly washed out.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
Strong oxidizers. Reducing agents. Lewis or mineral acids. Alkalies. Organic Halides Organic nitro
compounds. Aldehydes. Organic materials. Strong bases. Perchloric Acid. Strong bases. Ammonia.
Amines. Alkali metals and their hydroxides. Combustibles. Organic materials. Alkanol amines.
Aldehydes.
Finely divided metals. Tin. Zinc and its alloys. Galvanized Materials. Aluminum and its alloys. Copper
and its alloys. Hydrogen gas may be produced on prolonged contact with metals such as aluminum, tin,
lead and zinc.
Materials to Avoid:
Thermal decomposition products are toxic and may include Chlorine, flammable hydrogen gas,
corrosive hydrochloric acid gas, oxides of carbon, sulphur, aluminum and irritating gases.
Decomposition or Combustion
Products:
Sternpac, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 March 15
WHMIS Number :
00061452
Page 6 of 7
CANADIAN TDG ACT SHIPPING DESCRIPTION:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Aluminum Chloride Hydroxide Sulphate), Class 8, UN3264, PG III.
Label(s): Corrosives. Placard: Corrosives.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Aluminum Chloride Hydroxide Sulphate), Class 8, UN3264, PG III.
Label(s): Corrosive. Placard: Corrosive.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
This product has received NSF International certification under ANSI/NSF Standard 60 in the
Coagulation and Flocculation category under the official name of SternPAC. Only product
manufactured at Sternson Limited and whose container label bears the ANSI/NSF mark may be used in
potable water treatment applications. The maximum product dosage is 250 mg/L. (3)
CANADIAN FOOD AND DRUG
ACT/REGULATIONS:
Controlled Products Regulations Classification (WHMIS):
E: Corrosive
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Corrosive.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA: 2 Health, 0 Fire, 1 Reactivity (3)
Text22:
HMIS: 2 Health, 0 Fire, 1 Reactivity (3)
INTERNATIONAL
Not available.
16. OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons,
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical
Association, Ottawa, 1981.
7.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith
by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained
herein. This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1
Sternpac, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 March 15
WHMIS Number :
00061452
Page 7 of 7
Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9
Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2
Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6
Phone: (416) 259-8231 Facsimile: (416) 259-6175
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
Phone: (902) 468-9690 Facsimile: (902) 468-3085
____________________________________________________________________________________________________________
Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.