MATERIAL SAFETY DATA SHEET
OLEIC ACID
3. HAZARDS IDENTIFICATION
May cause skin and eye irritation. High vapour concentrations may cause drowsiness. May cause
central nervous system (CNS) depression. Can decompose at high temperatures forming toxic gases.
Contents may develop pressure on prolonged exposure to heat.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Product may be mildly irritating to the nose, throat and respiratory tract and may cause coughing and
sneezing. See "Other Health Effects" Section.
Inhalation:
Skin contact can cause irritation, especially under the finger nails (and other confined spaces such as
under rings or watch bands). Prolonged and repeated contact may lead to dermatitis. May cause
defatting, drying and cracking of the skin. May cause oil acne. Peroxide formation will increase the
irritancy of oleic acid.
Skin Contact:
A single, prolonged skin exposure is not likely to result in the absorption of toxic amounts of the material.
Skin Absorption:
Contact to the eye may cause irritation, redness and pain. Peroxide formation will increase the irritancy
of oleic acid.
Eye Contact:
This product may cause mild gastrointestinal discomfort.
Ingestion:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website: http:\\www.brenntag.ca
WHMIS#:
00064066
Index:
2008 July 08
PRODUCT IDENTIFICATION
Oleic Acid.
Product Name:
2008 July 08
Date of Revision:
Effective Date:
HCI2923/07A
(z)-9-Octadecenoic Acid.
Chemical Name:
Octadenenoic Acid; Red Oil; Pamolyn 100 FGK; Oleic Acid, Food Grade, Kosher; Emersol 213, 221,
229, 280, 6313.
Synonyms:
Monosaturated fatty acid.
Chemical Family:
C18H34O2.
Molecular Formula:
Cosmetics. Food additive. Chemical intermediate.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
Not WHMIS Regulated.
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Oleic Acid
112-80-1
---
99 - 100
Oleic Acid
Brenntag Canada Inc.
Date of Revision:
2008 July 08
WHMIS Number :
00064066
Page 2 of 6
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical attention
IMMEDIATELY.
Inhalation:
Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and
water. If irritation, redness, or a burning sensation develops and persists, repeat flushing and obtain
medical attention.
Skin Contact:
Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during
flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. IMMEDIATELY contact
local Poison Control Centre. Vomiting should only be induced under the direction of a physician or a
poison control centre. If spontaneous vomiting occurs, have victim lean forward with head down to
avoid breathing in of vomitus, rinse mouth and administer more water. IMMEDIATELY transport victim
to an emergency facility.
Ingestion:
This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has
occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to
prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial
resuscitation and appropriate chemotherapy if respiration is depressed.
Medical conditions that may be aggravated by exposure to this product include diseases of the skin,
eyes or respiratory tract.
Note to Physicians:
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation
or onset of pain. Strict adherence to first aid measures following any exposure is essential.
May cause central nervous system (CNS) depression. CNS depression is characterized by headache,
dizziness, drowsiness, nausea, vomiting and incoordination. Severe overexposures may lead to coma
and possible death due to respiratory failure. Prolonged and repeated contact may cause various forms
of dermatitis, including folliculitis and oil acne. Long-term intensive exposure to oil mist may cause
benign lung fibrosis.
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):
189. (3)
363. (4)
Not available.
Not available.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include oxides of carbon and irritating gases.
Hazardous Combustion
Products:
Do not direct a solid stream of foam into hot, burning pools. This may cause spattering and increase
fire intensity. Closed containers exposed to heat may burst. Spilled material may cause floors and
contact surfaces to become slippery.
Unusual Fire or Explosion
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Alcohol resistant foam. Dry chemical, carbon dioxide or water spray.
Fire Extinguishing Media:
FIRE FIGHTING
INSTRUCTIONS
Isolate materials that are not involved in the fire and protect personnel. Cool containers with flooding
quantities of water until well after the fire is out.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective
Equipment:
Oleic Acid
Brenntag Canada Inc.
Date of Revision:
2008 July 08
WHMIS Number :
00064066
Page 3 of 6
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons,
property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS.
Wear protective clothing. Collect product for recovery or disposal. For release to land, or storm water
runoff, contain discharge by constructing dykes or applying inert absorbent; for release to water, utilize
damming and/or water diversion to minimize the spread of contamination. Ventilate enclosed spaces.
Notify applicable government authority if release is reportable or could adversely affect the environment.
Containment and Clean-Up
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be
under internal pressure. These should be cooled and carefully vented before opening. A face shield
and apron should be worn. Vent container frequently, and more often in warm weather, to relieve
pressure.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing aerosols ( vapours or mists ). Avoid contact with
eyes, skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated
clothing thoroughly before re-use.
Other Precautions:
STORAGE
See below.
Storage Temperature (°C):
General exhaust is acceptable.
Ventilation Requirements:
Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers
closed. Do not expose sealed containers to temperatures above 89 °C. Avoid freezing! ( i.e. 12 to 17
°C ). Avoid direct sunlight.
Storage Requirements:
Confirm suitability of any material before using.
Special Materials to be Used for
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this
product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific
protective devices at your workplace.
ENGINEERING CONTROLS
General exhaust is acceptable. Local exhaust ventilation preferred. Make up air should be supplied to
balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as
sumps or pits where dense vapours may collect.
Engineering Controls:
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles
when there is potential for eye contact. Contact lenses should not be worn when working with this
material.
Eye Protection:
Gloves and protective clothing made from butyl rubber, nitrile rubber and viton should be impervious
under conditions of use. Prior to use, user should confirm impermeability. Do not use gloves or
protective clothing made from natural rubber. Discard contaminated gloves. (4)
Skin Protection:
No specific guidelines available. Respiratory protection should not be necessary unless the material is
heated or a mist created. A NIOSH/MSHA-approved air-purifying respirator equipped with organic
vapour cartridges for concentrations up to 1 000 ppm organic vapours. An air-supplied respirator if
concentrations are higher or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in
the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check
to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If
the seal is no longer good, you may need a new respirator. (4)
Respiratory Protection:
Wear regular work clothing. The use of coveralls is recommended. Locate safety shower and eyewash
station close to chemical handling area. Take all precautions to avoid personal contact.
Other Personal Protective
Equipment:
Oleic Acid
Brenntag Canada Inc.
Date of Revision:
2008 July 08
WHMIS Number :
00064066
Page 4 of 6
None established for this product.
EXPOSURE GUIDELINES
Liquid.
Colourless to pale yellow liquid.
Fatty acid odour.
Not available.
> 360.
12 - 17.
5.46 x 10-7.
Not applicable.
0.88 - 0.90.
880 - 900 kg/m³.
Not available.
Not available.
Practically insoluble in water.
0 %.
Not available.
5.36.
Not available.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
189. (3)
Flashpoint (°C):
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Oleic Acid
74 000 mg/kg (1)
---
---
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization
Data:
None known.
Synergistic Materials:
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not flammable.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
Temperatures above 89 °C. Keep tightly closed to protect quality. Avoid moisture contamination. Avoid
extended contact with air or oxygen. Oxygen exposure may lead to the formation of explosive peroxides.
(4) Avoid direct sunlight.
Conditions to Avoid:
Strong oxidizers. Strong acids. Reactive Metals. Strong bases. Reducing agents. Moisture.
Materials to Avoid:
Thermal decomposition products are toxic and may include oxides of carbon and irritating gases.
Decomposition or Combustion
Products:
Oleic Acid
Brenntag Canada Inc.
Date of Revision:
2008 July 08
WHMIS Number :
00064066
Page 5 of 6
Oleic Acid produced mild redness when 0.1 mL commercial grade (75%) was applied to rabbits eyes.
Complete clearing occurred in 72 hours. (4)
Application of 0.5 mL 10% Oleic Acid in Propylene Glycol to rabbit skin for 6 hours under cover
produced mild irritation (scored 2.3/8). (4)
High oral doses up to 19,200 mg/Kg have produced diarrhea and signs of central nervous system
depression with no deaths. (4)
Negative results were obtained in the guinea pig maximization test when Oleic Acid was tested for
skin sensitization. (4)
Fertility was not impaired in 4 male rats administered very high dietary levels of Oleic Acid (15%) for
16 weeks prior to mating. (4)
Oleic Acid has produced positive results in Chinese hamster lung fibroblasts and Saccharomyces
cerevisiae yeast, without metabolic activation. Negative results have been obtained in other short-term
mutagenicity tests using Salmonella typhimurium and Eschericheri coli with and without metabolic
activation. (4)
Other Studies Relevant to
Material:
12. ECOLOGICAL INFORMATION
Not available. Ecotoxicity is expected to be low based on the low water solubility.
Ecotoxicity:
Not available. May be harmful if allowed to enter drinking water intakes. Do not contaminate domestic or
irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
None required.
Deactivating Chemicals:
This information applies to the material as manufactured. Dispose of waste material at an approved
(hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal
regulations. Do not dispose of waste with normal garbage, or to sewer systems. Reevaluation of the
product may be required by the user at the time of disposal since the product uses, transformations,
mixtures and processes may influence waste classification.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue. Empty drums should be completely drained, properly bunged
and promptly returned to a drum reconditioner. Treat package in the same manner as the product.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s): Not applicable. Placard: Not applicable.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s): Not applicable. Placard: Not applicable.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
Oleic Acid
Brenntag Canada Inc.
Date of Revision:
2008 July 08
WHMIS Number :
00064066
Page 6 of 6
16. OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons,
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2007, American Conference of Governmental Industrial Hygienists, Cincinnati, 2007.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical
Association, Ottawa, 1981.
7.
NFPA 325M Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids, 1994 Edition, Quincy, MA, 1994.
8.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith
by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained
herein. This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1
Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9
Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2
Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6
Phone: (416) 259-8231 Facsimile: (416) 259-5333
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
Phone: (902) 468-9690 Facsimile: (902) 468-3085
____________________________________________________________________________________________________________
Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Not regulated.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA: 1 Health, 1 Fire, 0 Reactivity (4)
Text22:
HMIS: 1 Health, 1 Fire, 0 Reactivity (3)
INTERNATIONAL
Oleic Acid is found on the following inventories: EINECS (European Inventory of Existing Commercial Chemical Substances).
Not WHMIS Regulated.