MATERIAL SAFETY DATA SHEET
POTASSIUM SILICATE (ZACSIL) SOLUTION (ALL GRADES)
3. HAZARDS IDENTIFICATION
Harmful if inhaled or swallowed. Causes skin irritation. Causes severe eye irritation. See "Other Health
Effects" Section. Can decompose at high temperatures forming toxic gases. Contents may develop
pressure on prolonged exposure to heat.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Mists or sprays are irritating to eyes and respiratory tract. See "Other Health Effects" Section.
Inhalation:
Potassium Silicate may cause symptoms of skin irritation such as reddening, swelling, rash, scaling, or
blistering. Prolonged and repeated contact may lead to dermatitis. May cause defatting, drying and
cracking of the skin.
Skin Contact:
Not likely to be absorbed through the skin.
Skin Absorption:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website: http:\\www.brenntag.ca
WHMIS#:
00061287
Index:
2008 January 11
PRODUCT IDENTIFICATION
Potassium Silicate (Zacsil) Solution (All Grades).
Product Name:
2008 January 11
Date of Revision:
Effective Date:
HCI0130/08A
Silicic Acid, Potassium Salt (Water Solution).
Chemical Name:
Potassium Silicate; Potassium Water Glass; Zacsil Solution; Potassium Metasilicate; Soluble Potash
Water Glass; Electronics 200; Zacsil AG; Grade 30, 865, 18, 865D; Potassium Silicate (Zacsil)
Solution; Potassium Silicate 865 Zacsil; Potassium Silicate 200 Zacsil; Potassium Silicate 30 Zacsil;
Potassium Silicate Zacsil AG.
Synonyms:
Silicates.
Chemical Family:
K2SiO4.
Molecular Formula:
Electroplating, dyeing and printing. Chemical intermediate. Welding.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
D-2B: Toxic (skin and eye irritant)
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Potassium Silicate
1312-76-1
—
15 - 40
Potassium Silicate (Zacsil) Solution (All Grades)
Brenntag Canada Inc.
Date of Revision:
2008 January 11
WHMIS Number :
00061287
Page 2 of 6
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical attention
IMMEDIATELY.
Inhalation:
Prompt removal of the material is essential. Flush skin with running water for a minimum of 20 minutes.
Start flushing while removing contaminated clothing. If irritation persists, repeat flushing. Obtain
medical attention IMMEDIATELY. Do not transport victim unless the recommended flushing period is
completed or flushing can be continued during transport.
Skin Contact:
Prompt removal of the material is essential. Immediately flush eyes with running water for a minimum of
20 minutes. Hold eyelids open during flushing. If irritation persists, repeat flushing. Obtain medical
attention IMMEDIATELY. Do not transport victim until the recommended flushing period is completed
unless flushing can be continued during transport.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. IMMEDIATELY contact
local Poison Control Centre. Vomiting should only be induced under the direction of a physician or a
poison control centre. If spontaneous vomiting occurs, have victim lean forward with head down to
avoid breathing in of vomitus, rinse mouth and administer more water. IMMEDIATELY transport victim
to an emergency facility.
Ingestion:
This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has
occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to
prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial
resuscitation and appropriate chemotherapy if respiration is depressed.
Due to the severely irritating or corrosive nature of the material, swallowing may lead to ulceration and
inflammation of the upper alimentary tract with hemorrhage and fluid loss. Also, perforation of the
esophagus or stomach may occur, leading to mediastinitis or peritonitis and the resultant complications.
(3)
Activated charcoal mixture may be administered. To prepare activated charcoal mixture, suspend 50
grams activated charcoal in 400 mL water and mix thoroughly. Administer 5 mL/Kg, or 350 mL for an
average adult.
Medical conditions that may be aggravated by exposure to this product include neurological,
cardiovascular disorders, diseases of the skin, eyes or respiratory tract.
Note to Physicians:
Causes severe eye irritation. May cause corneal damage and conjunctivitis.
Eye Contact:
This product causes irritation, a burning sensation of the mouth and throat and abdominal pain.
Ingestion:
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation
or onset of pain. Strict adherence to first aid measures following any exposure is essential.
Symptoms of potassium poisoning may occur. These include slow heartbeat, accelerated breathing,
muscle weakness and, in severe cases, paralysis.
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):
Does not flash.
Not available.
Not available.
Not available.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include oxides of carbon, potassium, silicon and
irritating gases.
Hazardous Combustion
Products:
Not normally a fire hazard. Water content of product prevents ignition. Spilled material may cause
floors and contact surfaces to become slippery. Enforce NO SMOKING rules in area of use.
Unusual Fire or Explosion
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Potassium Silicate (Zacsil) Solution (All Grades)
Brenntag Canada Inc.
Date of Revision:
2008 January 11
WHMIS Number :
00061287
Page 3 of 6
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Use media appropriate for surrounding fire and/or materials.
Fire Extinguishing Media:
FIRE FIGHTING
INSTRUCTIONS
Fire-exposed containers should be kept cool by spraying with water to reduce pressure. Spilled material
may cause floors and contact surfaces to become slippery.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons,
property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS.
See Section 13, "Deactivating Chemicals". Wear protective clothing. Collect product for recovery or
disposal. For release to land, or storm water runoff, contain discharge by constructing dykes or
applying inert absorbent; for release to water, utilize damming and/or water diversion to minimize the
spread of contamination. Ventilate enclosed spaces. Notify applicable government authority if release
is reportable or could adversely affect the environment.
Containment and Clean-Up
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be
under internal pressure. These should be cooled and carefully vented before opening. A face shield
and apron should be worn.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing vapours, mists and aerosols. Avoid contact with
eyes, skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated
clothing thoroughly before re-use.
Other Precautions:
STORAGE
See below.
Storage Temperature (°C):
General exhaust is acceptable.
Ventilation Requirements:
Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers
closed. Do not expose sealed containers to temperatures above 40° C. Avoid moisture contamination.
Protect from direct sunlight. Protect against physical damage.
Storage Requirements:
Materials of construction for storing the product include: carbon steel, plastics and cast iron. Confirm
suitability of any material before using.
Special Materials to be Used for
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this
product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific
protective devices at your workplace.
ENGINEERING CONTROLS
General exhaust is acceptable. Local exhaust ventilation preferred. Make up air should be supplied to
balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as
sumps or pits where dense vapours may collect.
Engineering Controls:
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles
when there is potential for eye contact. Contact lenses should not be worn when working with this
material.
Eye Protection:
Gloves and protective clothing made from rubber should be impervious under conditions of use.
Discard contaminated gloves. Prior to use, user should confirm impermeability.
Skin Protection:
Potassium Silicate (Zacsil) Solution (All Grades)
Brenntag Canada Inc.
Date of Revision:
2008 January 11
WHMIS Number :
00061287
Page 4 of 6
No specific guidelines available. A NIOSH/MSHA-approved air-purifying respirator equipped with dust,
mist, fume cartridges for concentrations up to 50 mg/m³. An air-supplied respirator if concentrations are
higher or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in
the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check
to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If
the seal is no longer good, you may need a new respirator. (4)
Respiratory Protection:
Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical
handling area. Take all precautions to avoid personal contact.
Manufacturer's Recommended Exposure Level : 5 mg/m³. (3)
Other Personal Protective
Equipment:
None established for this product.
EXPOSURE GUIDELINES
Liquid.
Clear, colourless liquid.
Odourless.
Not available.
100. (3)
0. (3)
Not available.
Not available.
1.26 - 1.39. (3)
1 260 - 1 390 kg/m³
Not applicable.
< 1.0. (3)
Soluble in water.
0.
11 - 12. (3)
Not available.
Not applicable.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Potassium Silicate
> 1 000 mg/kg (4)
> 2 000 mg/kg (4)
---
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not flammable. Not normally a fire hazard. Water content of product prevents ignition.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition.
Conditions to Avoid:
Strong oxidizers. Lewis or mineral acids.
Materials to Avoid:
Thermal decomposition products are toxic and may include oxides of carbon, potassium, silicon and
irritating gases.
Decomposition or Combustion
Products:
Potassium Silicate (Zacsil) Solution (All Grades)
Brenntag Canada Inc.
Date of Revision:
2008 January 11
WHMIS Number :
00061287
Page 5 of 6
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization
Data:
None known.
Synergistic Materials:
None known.
Other Studies Relevant to
Material:
12. ECOLOGICAL INFORMATION
Harmful to aquatic life at low concentrations. Toxicity is associated with pH.
Potassium Silicate:
48-hour LC50 (Daphnia magna) = 3,390 mg/L (4)
96-hour LC50 (Fathead Minnow) = 2,730 mg/L (4)
Ecotoxicity:
Not available. Can be dangerous if allowed to enter drinking water intakes. Do not contaminate
domestic or irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
Neutralize carefully with weak acid to a pH of 6 to 9. Effervescence may result. Neutralization is
expected to be exothermic.
Deactivating Chemicals:
This information applies to the material as manufactured. Dispose of waste material at an approved
(hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal
regulations. Do not dispose of waste with normal garbage, or to sewer systems. Reevaluation of the
product may be required by the user at the time of disposal since the product uses, transformations,
mixtures and processes may influence waste classification.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue and can be dangerous. Empty drums should be completely
drained, properly bunged and promptly returned to a drum reconditioner. Do not expose such containers
to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury
or death. Treat package in the same manner as the product.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s): Not applicable. Placard: Not applicable.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s): Not applicable. Placard: Not applicable.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
Potassium Silicate (Zacsil) Solution (All Grades)
Brenntag Canada Inc.
Date of Revision:
2008 January 11
WHMIS Number :
00061287
Page 6 of 6
D-2B: Toxic (skin and eye irritant)
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Skin and Eye Irritant.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA: Health, Fire, Reactivity (Not available.)
Text22:
HMIS: 2 Health, 0 Fire, 0 Reactivity (3)
INTERNATIONAL
Not available.
16. OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons,
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical
Association, Ottawa, 1981.
7.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith
by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained
herein. This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1
Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9
Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2
Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6
Phone: (416) 259-8231 Facsimile: (416) 259-5333
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
Phone: (902) 468-9690 Facsimile: (902) 468-3085
____________________________________________________________________________________________________________
Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.