MATERIAL SAFETY DATA SHEET
PETRO BA, SOLID
3. HAZARDS IDENTIFICATION
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website: http:\\www.brenntag.ca
WHMIS#:
00066349
Index:
2007 February 06
PRODUCT IDENTIFICATION
Petro BA, Solid.
Product Name:
2007 February 06
Date of Revision:
Effective Date:
HCI5489/07A
Not applicable.
Chemical Name:
Petro BA Powder.
Synonyms:
Mixture of Surfactant and Sodium salts.
Chemical Family:
Not available.
Molecular Formula:
Anionic surfactant. Detergent ingredient. Metal cleaning.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
D-2B: Toxic (skin and eye irritant)
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Anionic Surfactant Blend
Not available.
---
60 - 100
Sodium Sulphate
7757-82-6
---
<2.5
Naphthalene
91-20-3
10 ppm (Skin)
Trace
*A4
The identity of one or more of the
ingredient(s) of this product have not
been disclosed by our supplier(s) and
we are not aware of any additional
health hazards due to these ingredients,
which are not already identified on this
MSDS.

A4 = Not classifiable as a human carcinogen. (ACGIH-A4).
Skin Notation: Contact with skin, eyes and mucous membranes can contribute to the overall exposure and may invalidate the TLV.
Consider measures to prevent absorption by these routes.
Petro BA, Solid
Brenntag Canada Inc.
Date of Revision:
2007 February 06
WHMIS Number :
00066349
Page 2 of 7
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical attention
IMMEDIATELY.
Inhalation:
Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and
water. If irritation, redness, or a burning sensation develops and persists, repeat flushing and obtain
medical attention.
Skin Contact:
Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during
flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. IMMEDIATELY contact
local Poison Control Centre. Vomiting should only be induced under the direction of a physician or a
poison control centre. If spontaneous vomiting occurs, have victim lean forward with head down to
avoid breathing in of vomitus, rinse mouth and administer more water. IMMEDIATELY transport victim
to an emergency facility.
Ingestion:
Treat symptomatically. Sodium salts have a hypothetical risk of hypernatremia. In addition to calcium
levels, sodium and phosphate levels should be monitored.
Medical conditions that may be aggravated by exposure to this product include neurological,
cardiovascular and skin disorders, diseases of the skin, eyes or respiratory tract.
Note to Physicians:
Harmful if swallowed. Causes skin and eye irritation. Dust is irritating to respiratory tract. See "Other
Health Effects" Section. Powdered material may form explosive dust-air mixtures. Can decompose at
high temperatures forming toxic gases.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Product may be mildly irritating to the nose, throat and respiratory tract and may cause coughing and
sneezing. Excessive contact with powder may cause drying of mucous membranes of nose and throat
due to absorption of moisture and oils. See "Other Health Effects" Section.
Inhalation:
Skin contact can cause irritation, especially under the finger nails (and other confined spaces such as
under rings or watch bands). Excessive contact with powder may cause drying of the skin due to
absorption of moisture and oils. May cause defatting, drying and cracking of the skin. Prolonged and
repeated contact may lead to dermatitis.
Skin Contact:
Not likely to be absorbed through the skin.
Skin Absorption:
This product causes irritation, redness and pain.
Eye Contact:
This product causes irritation, a burning sensation of the mouth and throat and abdominal pain. May
cause nausea and vomiting.
Ingestion:
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation
or onset of pain. Strict adherence to first aid measures following any exposure is essential.
In general, long-term exposure to high concentrations of dust may cause increased mucous flow in the
nose and respiratory system airways. This condition usually disappears after exposure stops.
Controversy exists as to the role exposure to dust has in the development of chronic bronchitis
(inflammation of the air passages into the lungs). Other factors such as smoking and general air
pollution are more important, but dust exposure may contribute. (4)
Sodium salts have a hypothetical risk of hypernatremia.
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):
>94. (3)
Not available.
Not available.
Not available.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include oxides of sulphur, sodium and irritating
gases.
Hazardous Combustion
Products:
Petro BA, Solid
Brenntag Canada Inc.
Date of Revision:
2007 February 06
WHMIS Number :
00066349
Page 3 of 7
Minimize air borne spreading of dust. This product may be capable of forming flammable dust clouds in
air. Avoid accumulation and dispersion of dust to reduce explosion potential.
Unusual Fire or Explosion
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
High voltage static electricity build-up is possible when significant quantities of dust are present.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Alcohol resistant foam. Dry chemical, carbon dioxide or water spray.
Fire Extinguishing Media:
FIRE FIGHTING
INSTRUCTIONS
Fire-exposed containers should be kept cool by spraying with water to reduce pressure. Spilled material
may cause floors and contact surfaces to become slippery. Clean up immediately to eliminate slipping
hazard. Do not allow to enter sewers or watercourses. Avoid accumulation and dispersion of dust to
reduce explosion potential.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons,
property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS.
Minimize air borne spreading of dust. Avoid accumulation and dispersion of dust to reduce explosion
potential. Eliminate all sources of ignition. Wear respirator, protective clothing and gloves. Avoid dry
sweeping. Do not use compressed air to clean surfaces. Vacuuming or wet sweeping is preferred.
Return all material possible to container for proper disposal.
Any recovered product can be used for the usual purpose, depending on the extent and kind of
contamination. Where a package (drum or bag) is damaged and / or leaking, repair it, or place it into an
over-pack drum immediately so as to avoid or minimize material loss and contamination of surrounding
environment. Replace damaged containers immediately to avoid loss of material and contamination of
surrounding atmosphere.
Collect product for recovery or disposal. For release to land, or storm water runoff, contain discharge
by constructing dykes or applying inert absorbent; for release to water, utilize damming and/or water
diversion to minimize the spread of contamination. Ventilate enclosed spaces. Notify applicable
government authority if release is reportable or could adversely affect the environment.
Containment and Clean-Up
Procedures:
7. HANDLING AND STORAGE
HANDLING
Avoid accumulation and dispersion of dust to reduce explosion potential. Ground and bond equipment
and containers to prevent a static charge buildup. Use spark-resistant tools. Use normal "good"
industrial hygiene and housekeeping practices. Clean up immediately to eliminate slipping hazard.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing dusts. Avoid contact with eyes, skin or clothing.
Wash thoroughly with soap and water after handling. Wash contaminated clothing thoroughly before re-
use.
Other Precautions:
STORAGE
Ideal storage temperature is 10-27 Deg. Celsius.
Storage Temperature (°C):
Ventilation should be explosion proof.
Ventilation Requirements:
Store in a cool, dry and well-ventilated area. Keep away from heat, sparks and flames. Keep
containers closed. Avoid moisture contamination. Prolonged storage may result in lumping or caking.
Protect from direct sunlight. Protect against physical damage.
Storage Requirements:
Confirm suitability of any material before using.
Special Materials to be Used for
Packaging or Containers:
Petro BA, Solid
Brenntag Canada Inc.
Date of Revision:
2007 February 06
WHMIS Number :
00066349
Page 4 of 7
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this
product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific
protective devices at your workplace.
ENGINEERING CONTROLS
General exhaust is acceptable. Local exhaust ventilation preferred. Make up air should be supplied to
balance air that is removed by local or general exhaust ventilation. Avoid accumulation and dispersion
of dust to reduce explosion potential. Ventilate low lying areas such as sumps or pits where dense dust
may collect.
Engineering Controls:
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
Safety glasses with side shields are recommended to prevent eye contact. Use dust-tight chemical
safety goggles when there is potential for eye contact. Contact lenses should not be worn when working
with this material.
Eye Protection:
Gloves and protective clothing made from neoprene, rubber or plastic should be impervious under
conditions of use. Prior to use, user should confirm impermeability. Discard contaminated gloves.
Skin Protection:
No specific guidelines available. A NIOSH/MSHA-approved air-purifying respirator equipped with dust,
mist, fume cartridges for concentrations up to 100 mg/m³. An air-supplied respirator if concentrations
are higher or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in
the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check
to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If
the seal is no longer good, you may need a new respirator. (4)
Respiratory Protection:
Avoid accumulation and dispersion of dust to reduce explosion potential. Wear regular work clothing.
The use of coveralls is recommended. Locate safety shower and eyewash station close to chemical
handling area. Take all precautions to avoid personal contact.
Other Personal Protective
Equipment:
Particulate Not Otherwise Classified:
ACGIH OSHA
10 mg/m³ - Inhalable particulate 50 mppcf* or 15 mg/m³ - Total Dust
3 mg/m�� - Respirable particulate 15 mppcf* or 5 mg/m³ - Respirable Fraction
* mppcf = million particles per cubic foot
EXPOSURE GUIDELINES
Solid.
Tan coloured powder.
Slightly acrid smell.
Not available.
Not applicable.
Not available. Decomposes
Negligible
Not applicable.
Not available.
Not available.
Not applicable.
Not applicable.
Soluble in water.
2. (3)
7.5 - 10. (3)
Not available.
Not applicable.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
10. STABILITY AND REACTIVITY
Petro BA, Solid
Brenntag Canada Inc.
Date of Revision:
2007 February 06
WHMIS Number :
00066349
Page 5 of 7
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Petro BA Powder
3 690 mg/kg (3)
---
---
Sodium Sulphate
7 070 mg/kg (3)
> 4 000 mg/kg (3)
---
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization
Data:
None known.
Synergistic Materials:
None known.
Other Studies Relevant to
Material:
12. ECOLOGICAL INFORMATION
Not available. May be harmful to aquatic life.
Ecotoxicity:
Not available. May be harmful if allowed to enter drinking water intakes. Do not contaminate domestic or
irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
None required.
Deactivating Chemicals:
This information applies to the material as manufactured. Reevaluation of the product may be required
by the user at the time of disposal since the product uses, transformations, mixtures and processes
may influence waste classification. Dispose of waste material at an approved (hazardous) waste
treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue and may be hazardous. Dispose of waste material at an
approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial
and federal regulations.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s): Not applicable. Placard: Not applicable.
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not flammable. Avoid accumulation and dispersion of dust to reduce explosion potential.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition. Avoid accumulation and
dispersion of dust to reduce explosion potential. Minimize air borne spreading of dust. Clean up
immediately to eliminate slipping hazard.
Conditions to Avoid:
Strong oxidizers. Lewis or mineral acids.
Materials to Avoid:
Thermal decomposition products are toxic and may include oxides of sulphur, sodium and irritating
gases.
Decomposition or Combustion
Products:
Petro BA, Solid
Brenntag Canada Inc.
Date of Revision:
2007 February 06
WHMIS Number :
00066349
Page 6 of 7
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s): Not applicable. Placard: Not applicable.
CERCLA-RQ:
Exemptions:
15. REGULATORY INFORMATION
CANADA
An ingredient of this product is included on the NDSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
D-2B: Toxic (skin and eye irritant)
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Skin and Eye Irritant.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA: Health, Fire, Reactivity (Not available.)
Text22:
HMIS: 2 Health, 1 Fire, 0 Reactivity (3)
INTERNATIONAL
Not available.
16. OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons,
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical
Association, Ottawa, 1981.
7.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith
by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained
herein. This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1
Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9
Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2
Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6
Petro BA, Solid
Brenntag Canada Inc.
Date of Revision:
2007 February 06
WHMIS Number :
00066349
Page 7 of 7
Phone: (416) 259-8231 Facsimile: (416) 259-6175
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
Phone: (902) 468-9690 Facsimile: (902) 468-3085
____________________________________________________________________________________________________________
Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.