MATERIAL SAFETY DATA SHEET
MAGRABAR ANTIFOAM PD-602, LIQUID
3. HAZARDS IDENTIFICATION
Low hazard for usual industrial or commercial handling. See "Other Health Effects" Section. Can
decompose at high temperatures forming toxic gases. Contents may develop pressure on prolonged
exposure to heat.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Contact with mist or spray may cause irritation of mucous membranes, coughing and difficulty in
breathing. See "Other Health Effects" Section.
Inhalation:
Prolonged, confined (especially under the finger nails, under rings or watch bands) or repeated
exposure may cause skin irritation. Prolonged and repeated contact may lead to dermatitis.
Skin Contact:
Not likely to be absorbed through the skin.
Skin Absorption:
This product may cause mild, transient irritation.
Eye Contact:
This product may cause mild gastrointestinal discomfort. Ingestion of very high levels may cause
abdominal cramps, diarrhea, nausea and vomiting.
Ingestion:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website: http:\\www.brenntag.ca
WHMIS#:
00066443
Index:
2007 August 08
PRODUCT IDENTIFICATION
Magrabar Antifoam PD-602, Liquid.
Product Name:
2007 August 08
Date of Revision:
Effective Date:
HCI5583/07C
Not available.
Chemical Name:
Not available.
Synonyms:
Mixture of Soybean Oil and White Mineral Oil.
Chemical Family:
Not available.
Molecular Formula:
Antifoam agent. Defoamer.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
Not WHMIS Regulated.
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Soybean Oil
8016-70-4
(10 mg/m3 )
60 - 100
White Mineral Oil
8042-47-5
(5 mg/m3 (O))
5 - 10
Magrabar Antifoam PD-602, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 August 08
WHMIS Number :
00066443
Page 2 of 6
4. FIRST AID MEASURES
FIRST AID PROCEDURES
If respiratory problems arise, move the victim to fresh air. Give artificial respiration ONLY if breathing
has stopped. Give cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain
medical advice IMMEDIATELY.
Inhalation:
Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and
water. If irritation, redness, or a burning sensation develops and persists, obtain medical advice.
Skin Contact:
Immediately flush eyes with running water for a minimum of 15 minutes. Hold eyelids open during
flushing. If irritation persists, repeat flushing. Obtain medical attention.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. DO NOT induce
vomiting. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing
in of vomitus, rinse mouth and administer more water. Obtain medical attention IMMEDIATELY.
Ingestion:
This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has
occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to
prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial
resuscitation and appropriate chemotherapy if respiration is depressed.
Medical conditions that may be aggravated by exposure to this product include diseases of the skin,
eyes or respiratory tract.
Note to Physicians:
Low hazard for usual industrial or commercial handling. Prolonged and repeated contact may cause
various forms of dermatitis, including folliculitis and oil acne. Long-term intensive exposure to oil mist
may cause benign lung fibrosis.
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):
282. (3)
Not available.
Not available.
Not available.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include: oxides of carbon and irritating gases.
Hazardous Combustion
Products:
Do not direct a solid stream of foam into hot, burning pools. This may cause spattering and increase
fire intensity. Closed containers exposed to heat may explode. Spilled material may cause floors and
contact surfaces to become slippery.
Unusual Fire or Explosion
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Foam. Dry chemical, carbon dioxide or water spray. Use carbon dioxide or dry chemical media for small
fires. If only water is available, use it in the form of a fog.
Fire Extinguishing Media:
FIRE FIGHTING
INSTRUCTIONS
Isolate materials that are not involved in the fire and protect personnel. The heat from a fire can cause
a build-up of pressure inside the containers which may rupture. Cool containers with flooding quantities
of water until well after the fire is out. (4)
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons,
Magrabar Antifoam PD-602, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 August 08
WHMIS Number :
00066443
Page 3 of 6
property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS.
Utilize a spill kit, if available. Wear protective clothing. Recover spilled material on non-combustible
absorbents, such as sand or vermiculite, and place in covered containers for disposal. Ventilate
enclosed spaces. Notify applicable government authority if release is reportable or could adversely
affect the environment.
Containment and Clean-Up
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be
under internal pressure. These should be cooled and carefully vented before opening. A face shield
and apron should be worn. Vent container frequently, and more often in warm weather, to relieve
pressure.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing aerosols ( vapours or mists ). Avoid contact with
eyes, skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated
clothing thoroughly before re-use.
Other Precautions:
STORAGE
See below.
Storage Temperature (°C):
General exhaust is acceptable.
Ventilation Requirements:
Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers
closed. Do not expose sealed containers to temperatures above 40° C. Avoid freezing! Protect against
physical damage. Protect from direct sunlight.
Storage Requirements:
Confirm suitability of any material before using.
Special Materials to be Used for
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this
product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific
protective devices at your workplace.
ENGINEERING CONTROLS
General exhaust is acceptable. Local exhaust ventilation preferred. Make up air should be supplied to
balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as
sumps or pits where dense vapours may collect.
Engineering Controls:
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles
when there is potential for eye contact. Contact lenses should not be worn when working with this
material.
Eye Protection:
Gloves and protective clothing made from nitrile rubber, rubber or plastic should be impervious under
conditions of use. Prior to use, user should confirm impermeability. Discard contaminated gloves.
Skin Protection:
No specific guidelines available. Respiratory protection should not be necessary unless the material is
heated or a mist created. Do not use compressed oxygen in hydrocarbon atmospheres. A
NIOSH/MSHA-approved air-purifying respirator equipped with organic vapour cartridges for
concentrations up to 50 mg/m3 oil mist. Use an air-supplied respirator if concentrations are high or
unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in
the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check
to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If
the seal is no longer good, you may need a new respirator. (4)
Respiratory Protection:
Wear regular work clothing. The use of coveralls is recommended. Locate safety shower and eyewash
station close to chemical handling area. Take all precautions to avoid personal contact.
Other Personal Protective
Equipment:
EXPOSURE GUIDELINES
SUBSTANCE
ACGIH TLV
(STEL)
OSHA PEL
(TWA) (STEL)
NIOSH REL
(TWA) (STEL)
Oil mist, mineral
10 mg/m³
5 mg/m3
---
5 mg/m3
10 mg/m3
Magrabar Antifoam PD-602, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 August 08
WHMIS Number :
00066443
Page 4 of 6
Soybean Oil
—
5 mg/m3
(Respirable
Fraction)
---
5 mg/mg
(Respirable
fraction)
---
White Mineral Oil
10 mg/m³
5 mg/m³ (Oil Mist)
---
5 mg/m³ (Oil Mist)
10 mg/m³ (Oil Mist)
Liquid.
Yellow amber liquid.
Mild odour.
Not available.
> 200. (3)
Not available.
< 0.1. (3)
Not available.
0.95 - 0.98. (3)
950 - 980 kg/m³. (3)
Not available.
Not available.
Emulsifiable in water.
Not available.
Not available.
Not available.
Not available.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
11. TOXICOLOGICAL INFORMATION
Meaningful toxicological test data could not be found for this product.
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
White Mineral Oil
> 5 000 mg/kg (3)
---
---
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization
Data:
None known.
Synergistic Materials:
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not flammable.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition. Avoid exposure to excessive
heat. Keep from freezing. Keep tightly closed to protect quality. Formation of oil mist.
Conditions to Avoid:
Strong oxidizers. Lewis or mineral acids.
Materials to Avoid:
Thermal decomposition products are toxic and may include: oxides of carbon and irritating gases.
Decomposition or Combustion
Products:
Magrabar Antifoam PD-602, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 August 08
WHMIS Number :
00066443
Page 5 of 6
None known.
Other Studies Relevant to
Material:
12. ECOLOGICAL INFORMATION
Not available. No adverse effect reported, toxicity to fish, aquatic species reported as negligible. (3)
Ecotoxicity:
Not available. May be harmful if allowed to enter drinking water intakes. Do not contaminate domestic or
irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
None required. Recover spilled material on adsorbents, such as sand or vermiculite, and place in
covered containers for disposal.
Deactivating Chemicals:
This information applies to the material as manufactured. Reevaluation of the product may be required
by the user at the time of disposal since the product uses, transformations, mixtures and processes
may influence waste classification. Dispose of waste material at an approved (hazardous) waste
treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue. Do not dispose of package until thoroughly washed out.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s): Not applicable. Placard: Not applicable.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s): Not applicable. Placard: Not applicable.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
Not WHMIS Regulated.
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Not regulated.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA: Health, Fire, Reactivity (Not available.)
Text22:
HMIS: 0 Health, 1 Fire, 0 Reactivity (3)
INTERNATIONAL
Not available.
16. OTHER INFORMATION
REFERENCES
Magrabar Antifoam PD-602, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 August 08
WHMIS Number :
00066443
Page 6 of 6
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons,
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical
Association, Ottawa, 1981.
7.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith
by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained
herein. This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1
Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9
Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2
Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6
Phone: (416) 259-8231 Facsimile: (416) 259-6175
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
Phone: (902) 468-9690 Facsimile: (902) 468-3085
____________________________________________________________________________________________________________
Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.